80da8c6f353d4a81bf0b609007a8a01a.jpg

姓名:陈霞

职称:教 授

联系方式:chenxia@sxu.edu.cn

介绍:

陈霞,1964年生,山西太原人,教授,博士生导师。山西省高等院校高评委评审专家,国家自然科学基金委化学科学部函评专家,教育部全国学位与研究生教育评估专家库成员,美国化学会、英国皇家学会、Wiley期刊以及Elsevier出版社所属部分期刊的审稿人,中国化学学会会员,山西省高等学校精品共享课程《分析化学》负责人。

教育与学术经历:

1. 2016/07-2016/10,美国西北大学,化学系,高级研究学者

2. 2011/02-2012/08,美国科罗拉多州立大学,化学系,访问教授

3. 2007/09-2008/09,以色列理工学院,化学系,博士后

4. 2002/09–2006/07,山西大学,无机化学,博士

5. 1996/09–1999/07,山西大学,应用化学,硕士

6. 1982/09–1986/07,山西大学,化学,学士

工作经历:

1. 2010/09-今,山西大学,化学化工学院,教授,博士生导师

2. 2002/06-2010/08,山西大学,化学化工学院,副教授,硕士生导师

3. 1999/08-2002/05,山西大学,化学化工学院,讲师

4. 1986/08-1996/07,山西省工程技术学院,化工系,助教、教师

讲授课程:

  本科生《分析化学》,《分析化学实验》

研究方向:

 金属有机化学,高分子化学

    1. 新型金属催化剂的设计与合成

    2. 可生物降解高分子材料的合成

    3. 烯烃催化聚合与共聚

    4. CO2活化与催化转化

主持科研项目:

1. 山西省重点学科引进海外该层次人才外专短期项目,2019/06-2024/05

2. 山西省科技厅重点研发项目,201703D321008,以二氧化碳为原料合成可降解塑料,2017/08-2019/12

3. 高分子物理与化学国家重点实验室开放课题基金项目, 2018-09,吡啶基烯醇铝配合物的合成及其催化性能研究,2018/09-2019/08

4. 山西省科技厅专利推广项目,2016001,高性能聚烯烃塑料催化剂的合成及应用,2016/07-2018/06

5. 高分子物理与化学国家重点实验室开放课题基金项目,2017-10,喹啉基亚胺金属配合物的合成及其性能研究,2017/09-2018/08

6. 山西省国际科技合作计划项目,2015081050,金属有机物在煤基化工中催化烯烃聚合的研究,2015/05-2017/05

7. 山西省回国留学人员科研项目,201310,乙烯基单体的催化聚合,2013/07-2015/12

8. 高分子物理与化学国家重点实验室开放课题基金项目,201408,烯醇式吡啶/喹啉氮氧镁、铝锌配合物的合成及催化环酯开环聚合,2014/09-2015/08

9. 国家自然科学基金面上项目,21072120,新型“Click”配体的设计及其金属配合物的制备与应用研究,2011/01-2013/12

10. 山西省科技攻关计划,20110321055,过渡金属烯烃聚合催化剂的制备与性能研究,2011/01-2013/12

11. 国家自然科学基金主任基金,20942009,由点击化学合成方法制备CGC型金属配合物及其催化性能,2010/01-2010/12

12. 教育部留学回国人员科研启动基金,20093601,以喹啉为母体的多齿金属配合物的合成及其烯烃聚合性能研究,2010/01-2011/12

13. 山西省留学回国人员科技活动择优资助获助项目,多齿金属配合物的合成及催化性能,2010/01-2011/12

14. 元素有机化学国家重点实验室申请的开放基金研究项目,0904,氮杂配位的多齿金属化合物合成及结构,2010/01-2010/12

15. 山西省回国留学人员科研资助项目,2009010,以取代喹哪啶为母体的多齿金属配合物的合成及其烯烃聚合催化性能的研究,2010/01-2011/12

16. 脱硫石膏综合利用,横向,2009/07-2010/12

17. 山西省自然科学基金,20051011,胺基--脒基金属配合物的合成及其结构研究, 2005/01-2007/12

18. 山西省自然科学基金,20001004β-二亚胺化合物的合成及结构研究,2000/01-2002/12

代表性论文:

1. Shuai Liu, Xia Chen*.The homoleptic bis( β-quinolylenolate) zinc catalysts for the ring-opening polymerization of ε-caprolactone: Kinetics and mechanism, Journal of Organometallic Chemistry, 2020, 930, 121596.

2. Lu Qin, Fangqin Cheng, Moris S. Eisen, Xia Chen*. Unexpected substituent’s effects on catalytic activity in the ring-opening polymerization of ε-CL and δ-VL catalyzed by β-pyridyl-enamino Al complexes, European Polymer Journal, 2020, 128, 109626

3. Ziyao Fan, Peng Wang, Chen Wu, Zhimin Liu, Xia Chen*. The Facile Synthesis of Lithium 2-RHydroquinolinide Complexes and Their High Activity toward ROP of ε‐Caprolactone, European Journal of Inorganic Chemistry, 2020, 400–406.

4. Lu Qin, Yue Zhang, Jianbin Chao, Jianhua Cheng, Xia Chen*. Four- and five-coordinate aluminum complexes supported by N,O-bidentate β-pyrazylenolate ligands: synthesis, structure and application in ROP of ε-caprolactone and lactide, Dalton Transactions, 2019, 48, 12315-12325.

5. Peng Wang, Jianbin Chao, Xia Chen*. Living ring-opening polymerization of e-caprolactone catalyzed by ß-quinolyl-enamino aluminium complexes: ligand electronic effect. Dalton Transactions, 2018, 47, 4118–4127

6. Yanshan Gao, Xia Chen, Jialong Zhang, Jiazhen Chen, Tracy L. Lohr*, and Tobin J. Marks*. Catalyst Nuclearity Effects on Stereo- and Regioinduction in Pyridylamidohafnium-Catalyzed Propylene and 1‑Octene Polymerizations, Macromolecules, 2018, 51, 2401-2410.

7. Lu Qin, Jianliang Bai, Yue Zhang, Xia Chen*. Synthesis of mono- and tetra-nuclear b-pyridylenolate zinc complexes and their catalysis toward the ring-opening copolymerization of ε-caprolactone and lactide, Journal of Organometallic Chemistry, 2018, 40-47.

8. Yihao Zhang, Xia Xiao, Jianliang Bai, Wei Cao, Xia Chen*. The insertion products of 2-picolyl lithium salt with benzonitrile and terephthalonitrile. Journal of Molecular Structure, 2018, 1153, 48-52.

9. Xiaomin Hao, Lu Qin, Mali Xu, Xia Chen*. Reactivity of 2-benzylpyridyl lithium toward benzonitrile derivatives: Addition versus elimination. Journal of Organometallic Chemistry, 2017, 853, 168-177.

10. Jianliang Bai, Xia Xiao, Yue Zhang, Jianbin Chao and Xia Chen*. β-Pyridylenolate zinc catalysts for the ring-opening homo- and copolymerization of ε-caprolactone and lactides. Dalton Transactions, 2017, 46, 9846–9858.

11. Jianliang Bai, Peng Wang, Wei Cao and Xia Chen*. Tautomer-selective derivatives of enolate, keton and enaminone by addition reaction of picoly-type anions with nitriles. Journal of Molecular Structure, 2017, 1128, 645-652.

12. Peng Wang, Xiaomin Hao, Jianhua Cheng, Jianbin Chao and Xia Chen*. Aluminum chelates supported by β-quinolyl enolate ligands: synthesis and ROP of ε-CL. Dalton Transactions, 2016, 45, 9088-9096.

13. Xia Xiao, Xiaomin Hao, Jianliang Bai, Jianbin Chao, Wei Cao and Xia Chen*. Synthesis, mechanism and ethylene polymerizationcatalysis of Ge(IV), Sn(II) and Zr(IV) complexesderived from substituted β-diketiminates. RSC Advances, 2016, 6, 60723-60728.

14. Bianxiang Zhang,* Yongqiang Kang, Lihua Yang, and Xia Chen*. A S-Arylation of 2-Mercaptoazoles with Diaryliodonium Triflates under Metal-Free and Base-Free Conditions. ChemistrySelect, 2016, 1, 1529 – 1532.

15. Lu Qin, Mali Xu, Xia Xiao and Xia Chen*. Insertion reaction of bis(silyl)methyl-lithium Li{CH[SiN(Me2)Me2]2} with RCN (R = But, Ph) and their transmetalation products. Journal of Organometallic Chemistry, 2016, 809, 1-6.

16. Mali Xu, Lu Qin, Tao Yan and Xia Chen*. Synthesis of pyridinyl-triazole metal complexes and their catalytic activity for ethylene polymerization. Chinese Journal of Synthetic Chemistry, 2016, 24, 16-20.

17. Peng Wang, Hai-fen Li, Xiao-yan Xue and Xia Chen*. Inserted Compounds of Lithium Silylquinolylamide Dimers [{8-(2-R-C9H5N)N(Me3Si)}Li·OEt2]2 (R = H or Me) with Dimethylcyanamide and Their Reactive Derivatives with Metal Halides. Dalton Transactions, 2015, 44, 4718-4725.

18. Peng Wang, Zhongyuan Li, Xiaoyan Xue, Xia Chen*. Synthesis and Structures of Symmetric Bridged 8-Aminoquinolinyl Derivatives and Their Zirconium Complexes. Chinese Journal Inorganic Chemistry, 2014, 30(10), 2360-2366.

19. Zhongyuan Li, Peng Wang, Xia Chen*. N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl) methyl]-1,1,1-trimethylsilanamine. Acta Crystallographica. 2014, E70, o59-60.

20. Congcong Wang, Xia Chen*. Synthesis and Structural Studies of a Kind of Amidocyanogen Fluorene Compound. Journal of Shanxi University, 2013, 36, 90-92.

21. Jie Cui, Xia Chen*. Synthesis and Characterization of 1-(1-phenyl-1H-1,2,3-trizol-etheynly) Indene. Journal of Shanxi University, 2013, 36, 96-98.

22. Xia Chen, Lucia Caporaso, Luigi Cavallo, and Eugene Y.-X. Chen*. Stereoselectivity in Metallocene-Catalyzed Polymerization of Renewable Methylene Butyrolactones: from Stereo-random to Stereo-perfect Polymers. Journal of the American ChemicalSociety, 2012, 134, 7278-7281.

23. Xiaohua Hou, Zhengguo Cai, Xia Chen*, Lin Wang, Carl Redshaw and Wen-Hua Sun*. N-(5,6,7-Trihydroquinolin-8-ylidene)-2-benzhydrylbenzen aminonickel Halide Complexes: Synthesis Characterization and Catalytic Behavior towards Ethylene Polymerization. Dalton Transactions, 2012, 41 (5), 1617 – 1623.

24. Xiaohua Hou, Tongling Liang, Wen-Hua Sun*, Carl Redshaw and Xia Chen*. 2-Substituted 8-(2-benzhydrylarylimino)-567-trihydroquinoline-NN’ nickel dichlorides: Synthesis characterization and catalytic behavior toward ethylene. Journal of Organometallic Chemistry, 2012, 708-709, 98-105.

25. Xia Chen*, Liping Zhang, Jianggang Yu, Xiang Hao, Hao Liu, Wen-Hua Sun*. Synthesis,characterization and ethylene oligomerization behavior of 2-(chloro-substituted-1H-benzoimidazol-2-yl)-6-(1-aryliminoethyl)pyridylnickel dihalides, Inorganica Chimica Acta, 2011, 370, 156-163.

26. Liping Zhang, Xiaohua Hou, Jianggang Yu, Xia Chen*, Xiang Hao, Wen-Hua Sun*. 2-(R-1H-Benzoimidazol-2-yl)-6-(1-aryliminoethyl)pyridyliron(II) dichlorides: Synthesis characterization and the ethylene oligomerization behavior, Inorganica Chimica Acta, 2011, 379, 70-79.

27. Xia Chen*, Xiaoyan Xue, Liping Zhang, Wen-Hua Sun*. Reaction of 9-trimethylsilylfluorenyllithium with nitriles: Organolithium compounds, Inorganic Chemistry Communications, 2011, 14, 235-237.

28. 王莉,畅功民,薛晓燕,黄淑萍,陈霞,一种六核笼状锂配合物的制备、结构及合成机理研究,无机化学学报2011, 27, 835-839.

29. Xia Chen*, Liping Zhang, Tongling Liang, Xiang Hao, Wen-Hua Sun*. 2-(7-Methyl-1H-benzoimidazol-2-yl)-6-(1-aryliminoethyl)pyridinylnickel Complexes: Synthesis Characterization and Their Ethylene Oligomerization, Comptes Rendus Chimie, 2010, 13, 1450-1459.

30. 王莉,郭建平,黄淑萍,陈霞.新型有机磷化合物的合成及其晶体结构,合成化学2010, 18, 579-581.

31. Xia Chen*, Lingling Guan, Moris S. Eisen, Haifen Li, Hongbo Tong, Liping Zhang, and Diansheng Liu*. Synthesis,InsertionReactivity,and Transmetalation Reactions of the Lithium Complex[{2-(6-R-Pyr)(Me3Si)}CHLi.OEt2]2(R=H or Me), Eur. J. Inorg. Chem. 2009, 33, 3488-3499.

32. Xiaoyan Xue, Xia Chen*, Hongbo Tong, Dichloridobis{6-methyl-2-[(trimethylsilylamino]pyridine-kN1}cobalt(II), Acta Crystallographica, 2009E65957-959.

33. 李海雰,陈霞,刘滇生*. 一种硼环合环己二胺手性配体的合成及表征,山西大学学报 20092376-78.

34. 王莉,王龙,黄淑萍,陈霞. PhP(C1)CH(SiMe3)2的合成及晶体结构分析,山西大学学报(自然科学版) , 2008, 31, 73-76.

35. Ling-Ling Guan, Xia Chen*, Hong-Bo Tong and Hai-Fen Li 9-(Chlorodimethylsilyl)fluorene, Acta Crystallographica, 2007E634602-4604.

36. Fang Xi, Xia Chen*, Jian-Ping Guo and Dian-Sheng Liu*. [Bis(trimethylsilyl)methyl] chloro(phenyl) phosphine, Acta Crystallographica, 2006E621944-1945.

37. 陈霞,郗芳,李文叶,刘滇生*. 桥联吡啶金属化合物的合成及结构研究,有机化学200525599-601.

38. Xia Chen, Li Wang, Jian-Ping Guo, Shu-Ping Huang and Dian-Sheng Liu*. Chain lithium complexes supported with bβ-diketiminate ligands containing pyridyl on the carbon framework, Mendeleev Communication, 2005, 15(4), 160-161.

39. Xia Chen, Sheng-Di Bai, Li Wang, and Dian-Sheng Liu*. Reactions of Bis(silyl-substituted) Methyllithium with α-Hydrogen-free Nitriles into 1,3,5-Triazines, Heterocyclics, 2005, 65(6), 1425-1430.

40. 陈霞,魏学红,郭建平,刘滇生*. 氧桥双β-二亚胺钴配合物的合成及结构,无机化学学报200521519-522.

41. Xia Chen, LiWang, Jian-Ping Guo, Shu-Ping Huang, Dian-Sheng Liu*. Catena-Poly [lithium(I)-μ-1-tert-butyl-3-(3-pyridyl)-N,N'-bis(trimethylsilyl)propane-1,3-diiminato], Acta Crystallographica, 2005E61574-576.

42. 王莉,陈霞*,黄淑萍,刘滇生*. Ph2PCH(SiMe3)2的合成及晶体结构分析,山西大学学报2004, 27, 2-4.

43. Xia Chen, Li Wang, Shu-Ping Huang, Dian-Sheng Liu*. 4- tert-Butyl-2-(4-pyridyl) -N,N-ß-bis(trimethylsilyl)propane-1,3-diimine, Acta Crystallographica, 2004E60473-475.

44. Xia Chen, Chenxia Du, Jian-Ping Guo, Xue-Hong Wei, Dian-Sheng Liu*. Addition Reactions of Bis(trimethylsilyl)methyl- and 1-Azaallyl-lithium with Cyanoamines into Triazines or β-Diketiminatolithium Compounds, Journal of Organometallic Chemistry, 2002655, 89-95

授权专利:

1. 陈霞王鹏一种喹啉基[N,N]双齿螯合金属催化剂及其合成方法和应用,发明专利,授权公告日:2019-02-26,专利号ZL 2017 1 0124147. 5

2. 陈霞郝晓敏,一种烯醇式吡嗪金属配合物及合成方法和应用,发明专利,授权公告日:2019-05-17,专利号ZL 20171 0433555. 9

3. 陈霞,肖霞,白建良,ε-己内酯和L-丙交酯共聚催化剂及共聚方法,发明专利,授权公告日:2019-05-17,专利号ZL 2017 1 0288852. 9

4. 陈霞,王鹏,冯国勤,樊文杰,一种1:1型烯醇式喹啉金属配合物及其合成方法和应用,发明专利,授权公告日:2016-03-30专利号:ZL 201410262403. 3

5. 陈霞,徐玛丽,李中元,王鹏,张静,一种1:1型烯醇式吡啶金属配合物及其制备方法和应用,发明专利,授权公告日:2016-02-10专利号:ZL 2014 1 0262376. X

6. 陈霞,徐玛丽,李中元,王鹏,张静,一种1:2型烯醇式吡啶金属配合物及其制备方法和应用, 发明专利,授权公告日:2016-02-10 ZL 201410262368. 5

7. 陈霞,王鹏,冯国勤,樊文杰,一种1:2型烯醇式喹啉铝配合物及其合成方法和应用,发明专利,授权公告日:2016-02-10专利号:ZL 201410262399. 0

8. 陈霞,王鹏,王聪聪,李中元一种以8-氨基喹啉为母体的金属配合物及其合成方法,发明专利,授权公告日:2015-07-01,专利号ZL 2013 1 0298187. 3

9. 陈霞白生弟,刘滇生2,4,6-三取代-均三嗪化合物及其合成方法,发明专利,授权公告日:2004-03-17专利号: ZL 01 120415.X

10. 周梅素,陈霞,魏学红,刘滇生,一种β-二亚胺金属配合物及其合成方法,发明专利,授权公告日:2004-05-01专利号:ZL 01 122341.3


院所中心
校内门户
TOP