姓名：韩高义
职称：教授
联系方式：han_gaoyis@sxu.edu.cn
介绍：韩高义1971，男，博士，山西大学分子科学研究所教授，博导，副所长。研究方向：材料化学。先后在Adv. Mater.、Angew. Chem. Int. Ed.、Carbon、Small、ACS Appl. Mater. Inter.、J. Power Sources等期刊发表论文近200篇，被SCI他引近4700次。先后主持国家自然科学基金5项，省部级项目6项。曾获山西省“五四”青年奖章，教育部新世纪优秀人才、“三晋英才”拔尖骨干人才等多项人才称号。目前担任山西省化工学会电化学储能专业委员会主任。
学习与工作经历：
2006/11-至今 山西大学分子科学研究所，教授
2002/6-2006/11 山西大学分子科学研究所，副教授
2002/5-2004/7 清华大学化学系，博士后
1997/9-2001/9 南京大学化学化工学院，博士
1999/6-2002/6 山西大学分子科学研究所，讲师
1996/6-1999/6 山西大学分子科学研究所，助教
1993/6-1996/6 山西大学分子科学研究所，硕士
1989/9-1993/6 山西大学化学系，学士
工作职责：负责分子科学研究所研究生工作
研究方向：能量转换与存储材料的研究与开发
讲授课程：材料化学、固体化学导论、现代化工分析技术
主持科研项目：
1. 国家自然科学基金委员会，集成项目，21574076，面向未来智能终端的碳纳米管电子技术研究，2022-01至2025-12，进行，主持第一子课题，100万元。
2. 国家自然科学基金委员会，面上项目，21574076，集于一体的柔性电化学电容器的构建及其性能研究，2016-01至2019-12，65万元，已结题，主持。
3. 国家自然科学基金委员会，NSFC-山西煤基低碳联合基金项目，U1510121，煤沥青基碳/石墨烯复合多孔材料的制备及其储能性质研究，2016-01至2018-12，59万元，已结题，主持。
4. 国家自然科学基金委员会，面上项目，21274082，柔性导电高分子/石墨烯基组装体的储能性质研究，2013-01至2014-12，38万元，已结题，主持。
5. 国家自然科学基金委员会，面上项目，21073115，碳复合纳米纤维及以其为载体的阳极电催化剂的制备、结构与性能研究，2011-01至2013-12，36万元，已结题，主持。
6. 国家自然科学基金委员会，青年基金项目，20604014，导电高分子在金属化的电纺有机纤维膜上的电化学生长特点及性能研究，2007-01至2009-12，25万元，已结题，主持。
7. 教育部，新世纪优秀人才支持计划项目，NCET-10-0926，化学类，2011-01至2013-12，50万元，已结题，主持。
8. 山西省自然科学基金委员会，面上项目，2014011016-1，石墨烯基复合材料的储能性质研究，2014-01至2016-12，3万元，已结题，主持。
9. 山西省自然科学青年委员会，青年基金项目，2007021008，电纺有机纤维膜的金属化及其用作电极的性能研究，2007-01至2009-12，5万元，已结题，主持。
代表性论文：
1. Zhang Xuehuan, Han Gaoyi, Zhu SHeng, Flash Nitrogen-Doped Carbon Nanotubes for Energy Storage and Conversion, Small , 2023, 202305406.
2. Zhu Sheng, Ding Lingtong, Zhang Xuehuan, Wang Kun, Wang XIao, Yang Feng, Han Gaoyi, Biaxially-Strained Phthalocyanine at Polyoxometalate@Carbon Nanotube Heterostructure Boosts Oxygen Reduction Catalysis, Angewante Cheimie-Int. Ed., 2023, 20230954
3. Feng Liping, Wang Mingju, Cahng Yunzhen, Song Hua, How Wenjing, Zhang Ying Xiao Yaoming, Zhu Sheng, Han Gaoyi, Polymerization-Pyrolysis-Derived Hierarchical Nitrogen-Doped Porous Carbon for Energetic Capacitive Energy Storage, ACS Applied Energy Materials , 2023, 6, 7147-7155.
4. Liu Huichao, Zhu Sheng, Chang Yunzhen, Hou Wenjing, Han Gaoyi, Pitch-based carbon materials: a review of their structural design, preparation and applications in energy storage, New Carbon Materials , 2023, 38, 459-473.
5. Liu Huichao, Zhu Sheng, Zhang Yu, Song Hua, Zhang Ying, Chang Yunzhen, Hou Wenjing, Han Gaoyi, Unveiling Superior Capacitive Behaviors of One-Pot Molten Salt-Engineered B, N Co-Doped Porous Carbon Sheets, Small , 2023, 202204119.
6. Hou Wenjing, Yang Meiling, Guo Yao, Ma Yuting, Guo Mengna, Xiao Yaoming, Han Gaoyi, Synergistic effects of caesium closo-dodecaborate on buried interface for efficient and stable perovskite solar cells, Journal of Colloid and Interface Science , 2023, 645, 472-482.
7. Bi Huan, Guo Yao, Guo Mengna, Ding Chao, Hayase Shuzi, Zou Hanjun, Shen Qing, Han Gaoyi, Hou Wenjing, Reduced interfacial recombination losses and lead leakage in lead-based perovskite solar cells using 2D/3D perovskite engineering, Journal of Power Sources , 2023,563,232825.
8. Liu Huichao, Shi Wanhui, Song Hua, Chang Yunzhen, Feng Liping, Hou Wenjing, Li Yanping, Zhao Yun, Zhu Sheng, Han Gaoyi, Dual-Role Salt-Assisted Construction of Hierarchically Porous Carbon for Supercapacitors with High Energy and Power Density, ACS Applied Energy Materials , 2023, 6, 222-232.
9. Liu Huichao, Song Hua, Feng Liping, Hou Wenjing, Chang Yunzhen, zhang Ying, Zhao Yun, Zhu Sheng, Han Gaoyi, One-pot molten salt-assisted synthesis of nitrogen-doped mesoporous carbon for high energy density supercapacitors, Applied Surface Science , 2022, 605, 154574.
10. Zhu Sheng, Chang Yunzhen, Hou Wenjing, Li Yanping, Ni Jiangfeng, Han Gaoyi, Molten-salt directed mesopore engineering of carbon nanotubes for energetic quasi-solid-state supercapacitors, Carbon , 2022, 200, 75-83.
11. Hou Wenjing, Guo Mengna, Chang Yunzhen, Zhu SHeng, Bi Huan, Shen Qing, Xiao Yaoming, Han Gaoyi, In situ lead oxysalt passivation layer for stable and efficient perovskite solar cells, Chemical Communications , 2022, 58, 12708-12711.
12. Zhu Sheng, Zhang Fei, Lu Hai-Gang, Sheng Jian, Wang Lina, Li Si-Dian, Han Gaoyi, Li Yan, Flash Nitrogen-Doped Graphene for HighRate Supercapacitors Flash Nitrogen- Doped Graphene for HighRate Supercapacitors, ACS Materials Lett ers, 2022, 4, 1863−1871.
13. Bi H, Han GY, Guo MN, Ding C, Zou HJ, Shen Q*, Hayase S*, Hou WJ*, Multistrategy Preparation of Efficient and Stable Environment-Friendly Lead-Based Perovskite Solar Cells, ACS Applied Materials & Interfaces , 2022, 14, 35513-35521.
14. Shi WH, Wang ZW, Song H, Chang YZ*, Hou WJ*, Li YP, Han GY*, High-Sensitivity and Extreme Environment- Resistant Sensors Based on PEDOT:PSS@PVA Hydrogel Fibers for Physiological Monitoring, ACS Applied Materials & Interfaces , 2022, 14, 35114-35125.
15. Bi H, Guo Y, Guo MN, Ding C, Hayase S, Mou T, Shen Q*, Han GY*, Hou WJ*, Highly efficient and low hysteresis methylammonium-free perovskite solar cells based on multifunctional oteracil potassium interface modification, Chemical Engineering Journal , 2022, 439, 135671.
16. Bi H, Han GY, Guo MN, Ding C, Hayase S*, Zou HJ, Shen Q*, Guo Y, Hou WJ*, Top-Contacts-Interface Engineering for High-Performance Perovskite Solar Cell With Reducing Lead Leakage, Solar RRL , 2022, 2200352.
17. Zhu S, Wang LN, Gu CY, Liu HC, Mu YW*, Ni JF*, Han GY*, Boosting capacitive performance of nitrogen-doped carbon by atomically dispersed iron, Journal of Power Sources , 2022, 532, 231335.
18. Hu RJ, Hou WJ*, Han GY*, Ou T, Chang YZ, Xiao YM, Interfacial chemical bridge constructed by l-cysteine for highly efficient perovskite solar cells, Materials Research Bulletin , 2022, 149, 111698.
19. Niu CX, Song H, Chang YZ*, Hou WJ*, Li YP, Zhao Y, Xiao YM, Han GY*, Amorphous MoSx electro-synthesized in alkaline electrolyte for superior hydrogen evolution, Journal of Alloys and Compounds , 2022, 900, 163509.
20. Liu HC, Song H, Hou WJ, Chang YZ, Zhang Y, Li YP, Zhao Y, Han GY, Coal tar pitch-based hierarchical porous carbons prepared in molten salt for supercapacitors, Materials Chemistry and Physics , 2021, 265, 124491
21. Shi WH, Han GY*, Chang YZ, Song H, Hou WJ, Chen Q, Using Stretchable PPy@PVA Composites as a High-Sensitivity Strain Sensor To Monitor Minute Motion, ACS Applied Materials & Interfaces, 2020, 12, 45373-45382
22. Hou WJ, Han GY, Ou T, Xiao YM, Chen Q, An Efficient and Stable Perovskite Solar Cell with Suppressed Defects by Employing Dithizone as a Lead Indicator, Angewandte Chemie-International Edition , 2020, 59, 21409-21413
23. Wang N, Wang X, Zhang Y, Hou WJ, Chang YZ, Song H, Zhao Y, Han GY*, All-in-one flexible asymmetric supercapacitor based on composite of polypyrrole-graphene oxide and poly(3,4-ethylenedioxythiophene), Journal of Alloys and Compounds , 2020, 835, 155299
24. Wang N, Hou WJ, Chang YZ, Song H, Li HG, Li YP, Han GY*, Binder-free hydrogen storage composite Co9S8/rGO: A prospective anode for flexible energy storage device with high energy density, Electrochimica Acta , 2020, 354, 136734
25. Niu CX, Han GY*, Song H, Yuan SF, Hou WJ, Intercalation pseudo-capacitance behavior of few-layered molybdenum sulfide in various electrolytes, Journal of Colloid and Interface Science , 2020, 561, 117-126
26. Wang N, Han GY, Chang YZ, Hou WJ, Xiao YM, Li HG, Preparing Ni3S2 composite with neural network-like structure for high-performance flexible asymmetric supercapacitors, Electrochimica Acta , 2019, 317, 322-332
27. Chang Yahui, Wang Na, Han Gaoyi*, Li Miaoyu, Xiao Yaoming, Li Honggang, The properties of highly compressible electrochemical capacitors based on polypyrrole/ melamine sponge-carbon fibers, Journal of Alloys and Compounds , 2019, 786, 668-676.
28. Wang Na, Han Gaoyi*, Song Hua, Xiao Yaoming*, Li Yanping, Zhang Ying, Wang Hongfei, Integrated flexible supercapacitor based on poly (3, 4-ethylene dioxythiophene) deposited on Au/porous polypropylene film/Au, Journal of Power Sources , 2018, 395, 228-236.
29. Wang Na, Han Gaoyi*, Xiao Yaoming*, Li Yanping, Song Hua, Zhang Ying, Polypyrrole /graphene oxide deposited on two metalized surfaces of porous polypropylene films as all-in-one flexible supercapacitors, Electrochimica Acta , 2018, 270, 490-500.
30. Hou WJ, Xiao YM*, Han GY*, An Interconnected Ternary MIn2S4 (M = Fe, Co, Ni) Thiospinel Nanosheet Array: A Type of Efficient Platinum-Free Counter Electrode for Dye-Sensitized Solar Cells， Angewandte Chemie - Int Ed ，2017, 56, 9146-9150
31. Li HG, Xiao YM*, Han GY*, Hou WJ，Honeycomb-like poly(3,4-ethylenedioxy thiophene) as an effective and transparent counter electrode in bifacial dye-sensitized solar cells， Journal of Power Sources ，2017, 342, 709-716
32. Liu CX, Han GY*, Chang YZ, Xiao YM*, Zhou HH, Shi GQ，High-performance supercapacitors based on the reduced graphene oxide hydrogels modified by trace amounts of benzenediols, Chemical Engineering Journal , 2017, 328, 25-34.
33. Chang YH, Han GY*, Xiao YM*, Chang YZ, Song H, Li MY, Li YP, Zhang Y, Internal tandem flexible and compressible electrochemical capacitor based on polypyrrole/carbon fibers, Electrochimica Acta, 2017, 257, 335-344.
34. Chang YH, Han GY*, Chang YZ, Xiao YM*, Hou WJ, Zhou W, Flexible and compressible electrochemical capacitors based on polypyrrole/carbon fibers integrated into sponge, Journal of Alloys and Compounds , 2017, 708, 1206-1215.
35. Li MY, Zheng HJ, Han GY*, Xiao YM, Li YP, Facile synthesis of binary PtRu nanoflowers for advanced electrocatalysts toward methanol oxidation, Catalysis Communications , 2017, 92, 95-99.
36. Yue JY, Xiao YM*, Li YP*, Han GY, Multifunctional stannum oxide compact bilayer modified by europium and erbium respectively doped ytterbium fluoride for high-performance dye-sensitized solar cell, Electrochimica Acta , 2017, 248, 333-341.
37. Hou WJ, Xiao YM*, Han GY*, Zhang Y, Chang YZ, Titanium dioxide/zinc indium sulfide hetero-junction: An efficient photoanode for the dye-sensitized solar cell, Journal of Power Sources , 2016, 328, 578-585.
38. Hou WJ, Xiao YM*, Han GY*, Fu DY, Wu RF, Serrated, flexible and ultrathin polyaniline nanoribbons: An efficient counter electrode for the dye-sensitized solar cell, Journal of Power Sources , 2016, 322, 155-162.
39. Hou WJ, Xiao YM*, Han GY*, Zhou HH, Electro-polymerization of polypyrrole/multi-wall carbon nanotube counter electrodes for use in platinum-free dye-sensitized solar cells, Electrochimica Acta , 2016, 190, 720-728.
40. Liu CX, Han GY*, Chang YZ, Xiao YM, Li MY, Zhou W, Monolithic porous carbon derived from polyvinyl alcohol for electrochemical double layer capacitors, Electrochimica Acta , 2016, 188, 175-183.
41. Yuan W, Han GY*, Chang YZ, Li MY, Xiao YM*, Zhou HH, Zhang Y, Li YP, Performance of flexible capacitors based on polypyrrole/ carbon fiber electrochemically prepared from various phosphate electrolytes, Applied Surface Science , 2016, 387, 902-911.
42. Yuan W, Han GY*, Xiao YM, Chang YZ, Liu CX, Li MY, Li YP, Zhang Y, Flexible electrochemical capacitors based on polypyrrole/ carbon fibers via chemical polymerization of pyrrole vapor, Applied Surface Science , 2016, 377, 274- 282.
43. Xiao YM*, Han GY, Wu JH, Lin JY, Efficient bifacial perovskite solar cell based on a highly transparent poly(3,4-ethylenedioxythiophene) as the p-type hole-transporting material, Journal of Power Sources , 2016, 306, 171-177.
44. Zhou HH*, Han GY, One-step fabrication of heterogeneous conducting polymers-coated graphene oxide/carbon nanotubes composite films for high-performance supercapacitors, Electrochimica Acta , 2016, 192, 448-455.
45. Zhou HH*, Zhai HJ, Han GY, Superior performance of highly flexible solid-state supercapacitor based on the ternary composites of graphene oxide supported poly(3,4 -ethylenedioxythio phene)-carbon nanotubes, Journal of Power Sources , 2016, 323, 125- 133.
46. Zhou W, Han GY*, Xiao YM, Chang YZ, Yuan W, Li YP, Liu CX, Zhang YZ, Polypyrrole doped with dodecyl benzene sulfonate electrodeposited on carbon fibers for flexible capacitors with high-performance, Electrochimica Acta , 2015, 176, 594- 603.
47. Xiao YM*, Han GY*, Efficient hydrothermal-processed platinum nickel bimetallic nano- catalysts for use in dye-sensitized solar cells, Journal of Power Sources , 2015, 294, 8-15.
48. Xiao YM*, Han GY*, Wu RF, Li YP, Li MY, Efficiently cubic platinum-cobalt bimetallic nano-catalysts for use in low-cost dye-sensitized solar cells, Electrochimica Acta , 2015, 174, 770-777.
49. Xiao YM*, Han GY*, Chang YZ, Zhang Y, Li YP, Li MY, Investigation of perovskite- sensitized nanoporous titanium dioxide photoanodes with different thicknesses in perovskite solar cells, Journal of Power Sources , 2015, 286, 118-123.
50. Xiao YM*, Han GY*, Li YP, Li MY, Lin JY*, Three-dimensional hollow platinum-nickel bimetallic nanoframes for use in dye-sensitized solar cells, Journal of Power Sources , 2015, 278, 149-155.
51. Xiao YM*, Han GY*, Zhou HH, Li YP, Lin JY*, Nickel sulfide counter electrodes enhanced by hydro sulphuric acid hydrothermal treatments for use in Pt-free dye-sensitized solar cells, Electrochimica Acta , 2015, 155, 103- 109.
52. Zhou HH*, Han GY*, Chang YZ, Fu DY, Xiao YM, Highly stable multi-wall carbon nanotubes @poly(3,4- ethylenedioxythiophene)/poly(styrene sulfonate) core-shell composite with three-dimensional porous nano-network for electrochemical capacitors, Journal of Power Sources , 2015, 274, 229- 236.
53. Zhou HH*, Han GY*, Fu DY, Chang YZ, Xiao YM, Zhai HJ, Petal-shaped poly(3,4- ethylenedioxy thiophene)/sodium dodecyl sulfate-graphene oxide intercalation composites for high-performance electrochemical energy storage, Journal of Power Sources , 2014, 272, 203-210.
54. Chang YZ, Han GY*, Fu DY, Liu FF, Li MY, Li YP, Larger-scale fabrication of N-doped graphene-fiber mats used in high-performance energy storage, Journal of Power Sources , 2014, 252, 113-121.
55. Liu ZY, Fu DY, Liu FF, Han GY*, Liu CX, Chang YZ, Xiao YM, Li MY, Li SD, Mesoporous carbon nanofibers with large cage-like pores activated by tin dioxide and their use in supercapacitor and catalyst support, Carbon , 2014, 70, 295-307.
56. Chang YZ, Han GY*, Fu DY, Liu FF, Li MY, Li YP, Liu CX, Paper-like N-doped graphene films prepared by hydroxyl amine diffusion induced assembly and their ultrahigh-rate capacitive properties, Electrochimica Acta , 2014, 115, 461- 470.
57. Xiao YM*, Han GY*, Chang YZ, Zhou HH, Li MY, Li YP, An all-solid-state perovskite- sensitized solar cell based on the dual function polyaniline as the sensitizer and p-type hole-transporting material, Journal of Power Sources , 2014, 267, 1-8.
58. Xiao YM*, Han GY*, Li YP, Li MY, Wu JH*, Electrospun lead-doped titanium dioxide nanofibers and the in situ preparation of perovskite-sensitized photoanodes for use in high performance perovskite solar cells, Journal of Materials Chemistry A , 2014, 2, 16856-16862.
59. Xiao YM*, Han GY*, Li YP, Li MY, Chang YZ, Wu JH, Preparation of high performance perovskite -sensitized nanoporous titanium dioxide photoanodes by in situ method for use in perovskite solar cells, Journal of Materials Chemistry A , 2014, 2, 16531-16537.
60. Zhou HH*, Han GY*, Xiao YM, Chang YZ, Zhai HJ, Facile preparation of polypyrrole/ graphene oxide nano composites with large areal capacitance using electrochemical codeposition for supercapacitors, Journal of Power Sources , 2014, 263, 259- 267.
61. Xiao YM*, Han GY*, Li YP, Li MY, Chang YZ, High performance of Pt-free dye-sensitized solar cells based on two-step electropolymerized polyaniline counter electrodes, Journal of Materials Chemistry A , 2014, 2, 3452-3460.
62. Yunzhen Chang, Gaoyi Han, Jinping Yuan, Dongying Fu, Feifei Liu, Sidian Li, Using hydroxylamine as reducer to prepare N-doped graphene hydrogels used in high-performance energy storage, Journal of Power Sources, 238 (2013) 493-500.
63. Zhao Hua, Han Gaoyi, Chang Yunzhen, Li Miaoyu, Li Yanping, The capacitive properties of amorphous manganese dioxide electrodeposited on different thermally- treated carbon papers, Electrochemica Acta, 2013, 91, 50-57.
64. Fu Dongying, Han Gaoyi, Chang Yunzhen, Dong Jianhua, The synthesis and properties of ZnO-graphene nano hybrid for photodegradation of organic pollutant in water, Materials Chemistry and Physics, 2012, 132, 673-681.
65. Chang Yunzhen, Han Gaoyi, Li Miaoyu, Gao Fei, Graphene-modified carbon fiber mats used to improve the activity and stability of Pt catalyst for methanol electrochemical oxidation, Carbon, 2011, 49, 5158-5165.
66. Jin Ming, Han Gaoyi, Chang Yunzhen, Zhao Hua, Zhang Huanyu, Flexible electrodes based on polypyrrole/manganese dioxide/polypropylene fibrous membrane composite for supercapacitor, Electrochimica Acta, 2011, 56, 9838-9845.
67. Miaoyu Li, Yunzhen Chang, Gaoyi Han, Bisheng Yang, Platinum nanoparticles supported on electrospinning-derived carbon fibrous mats by using formaldehyde vapor as reducer for methanol electrooxidation, Journal of Power Sources, 2011, 196, 7973-7978.
68. Xiaomin Liu, Miaoyu Li, Gaoyi Han*, Jianhua Dong, The catalysts supported on metallized electrospun polyacrylonitrile fibrous mats for methanol oxidation, Electrochim. Acta , 2010, 55, 2983-2990.
69. Miaoyu Li, Shizhen Zhao, Gaoyi Han*, Binsheng Yang, Electrospinning-derived carbon fibrous mats improving the performance of commercial Pt/C for methanol oxidation, J. Power Sources , 2009, 191, 351-356.
70. Li Miaoyu, Han Gaoyi*, Yang Binsheng, Fabrication of the Catalytic Electrodes for Methanol Oxidation on Electrospinning-Derived Carbon Fibrous Mats, Electrochem. Commun. 2008, 10, 880-883.
71. Bin Guo, Shizhen Zhao, Gaoyi Han*, Liwei Zhang, Continuous thin gold films electroless deposited on fibrous mats of polyacrylonitrile and their electrocatalytic activity towards the oxidation of methanol, Electrochim. Acta 2008, 53, 5174–5179.
72. Gaoyi Han*, Bin Guo, Liwei Zhang, Binsheng Yang, Conductive Gold Films Assembled on Electrospun Poly (methyl methacrylate) Fibrous Mat, Adv. Mater., 2006, 18, 1709-1712.
73. Goyi Han, Gaoquan Shi，Electrochemical actuator based on single-layer polypyrrole film, Sens. Actuat. B, 2006, 113, 259–264.
74. Gaoyi Han, Gaoquan Shi，Conducting polymer electrochemical actuator made of high-strength three-layered composite films of polythiophene and polypyrrole， Sens. Actuat. B, 2004, 99, 525–531.
75. Han Gaoyi, Yang Pin, Synthesis and characterization of water-insoluble and water- soluble dibutyltin (IV) porphinate complexes based on the tris(pyridinyl) porphyrin moiety and their anti-tumor, J. Inorg. Biochem. , 2002, 91, 230–236.
授权专利：
1. 毕欢 侯文静 韩高义，一种应用于铅基钙钛矿太阳能电池的界面修饰分子，国家发明专利，ZL 202210501227.9.，授权日期：2023年3月
2. 韩高义 石婉辉 常云珍，一种极端环境耐受型高灵敏度应变传感器的制备方法，国家发明专利，ZL202210056557.1，授权日期：2023年9月
3. 韩高义 王娜 常云珍， 一种柔性的二硫化三镍石墨烯复合电极材料的制备方法,国家发明专利，ZL201910195367.6.，授权日期：2020年2月
4. 韩高义 马文辉 常云珍，一种具有管状结构的石墨烯膜电极的制备方法, 国家发明专利， ZL201810377450.0， 授权日期: 2020年4月
5. 韩高义 马文辉 常云珍，一种石墨烯膜电极材料的制备方法, 国家发明专利，L201810377555.6.，2019年9月
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